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Poly (p-phenylene sul de) [IUPAC: poly(sulfanediyl-1,4-phenylene) (trade name: Ryton) (PPS) is synthesized by the reaction of sodium sul de with p-dichlorobenzene in a polar solvent such as 1-methyl-2-pyrrolidinone (NMP) at about 250 C and 1.1 MPa (160 psi) [Fahey and Geibel, 1996; Hill and Brady, 1988; Lopez and Wilkes, 1989]. The reaction may be more complicated than a simple nucleophilic aromatic substitution [Koch and Heitz, 1983]. PPS undergoes a slow curing process when heated above the melting point in air. Curing involves chain extension, oxidation, and crosslinking, but is poorly understood. There is spectroscopic evidence for crosslinking via sulfur, oxygen, and aromatic bridges between polymer chains [Hawkins, 1976]. vb.net code to merge pdf files Auto merge 2 PDF file to 1 PDF | The ASP.NET Forums
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May 3, 2014 · Merge multiple PDF files into one using C#. In the following ... VB.NET code sample: merge PDF. Copy ' Find all pdf documents in input folder. Uncrosslinked PPS is a highly ($60%) crystalline polymer with Tm 285 C and Tg 85 C. It is rated for continuous service at 200 240 C, placing PPS between the polysulfones and the polyketones. It has inherent ame resistance, and its stability toward both organic and aqueous environments is excellent. PPS is comparable to polysulfones and polyketones in resistance to acids and bases but is somewhat less resistant to oxidants. The resistance of PPS to organic solvents is comparable to that of polyamides and polyketones. More than 20 million pounds of PPS are produced annually in the Unites States. Applications of PPS include automotive (components requiring heat and uid resistance, sockets and re ectors for lights), consumer (microwave oven components, hair-dryer grille), industrial (oil eld downhole components, motor insulation, pumps and valves), blends with uorocarbon polymers (release coating for cookware, appliances, molds), and protective coatings (valves, pipe, heat exchangers, electromotive cells). PPS is an alternative to traditional thermosetting plastis in some of these applications. Aromatic polyimides are synthesized by the reactions of dianhydrides with diamines, for example, the polymerization of pyromellitic anhydride with p-phenylenediamine to form poly(pyromellitimido-1,4-phenylene) (XLV) [de Abajo, 1988, 1999; Hergenrother, 1987; Johnston et al., 1987; Maier, 2001]. Solubility considerations sometimes result in using the half acid half ester of the dianhydride instead of the dianhydride. The direct production of high-molecular-weight aromatic polyimides in a one-stage polymerization cannot be accomplished because the polyimides are insoluble and infusible. The polymer chains precipitate from the reaction media before high molecular weights are obtained. Polymerization is accomplished by a two-stage process. The rst stage involves an amidation reaction carried out in a polar aprotic solvent such as NMP or N; N-dimethylacetamide (DMAC) to produce a high-molecular-weight poly(amic acid) (XLIV). Processing of the polymer can be accomplished only prior to the second stage, at which point it is still soluble and fusible. It is insoluble and infusible after the second stage of the process. The poly(amic acid) is formed into the desired physical form of the nal polymer product (e.g., lm, ber, laminate, coating) and then the second stage of the process is performed. The poly(amic acid) is cyclodehydrated to the polyimide (XLV) by heating at temperatures above 150 C. vb.net itextsharp merge pdf files Merge PDF files from C# / VB.NET applications - GemBox
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