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Polyimide lms nd applications as insulation for electric motors and missile and aircraft wire and cable There is also some processing of PI by powder technology (lowtemperature forming followed by sintering) and compression molding (requiring higher pressures than normal) to form such automotive and aircraft engine parts as bushings, seals, piston rings, and bearings The lack of easy processability initially limited the utilization of this high-performance material Several different modi cations of the polyimide system have successfully produced.

materials that are more readily processable at the fully imidized state. Appropriate dianhydrides and diamines are used to increase solubility and melt processability by decreasing molecular order and packing. This is done by introducing exible segments [aliphatic, O, S, C O, SO2, C(CH3)2, C(CF3)2] into the polyimide chains or bulky side groups (phenyl, t-butyl) or using 1,3-disubstituted reactants instead of 1,4 reactants [de Abajo, 1999; Sillion, 1999; Yokota et al., 2001]. Polyetherimides (PEI) are polyimides containing suf cient ether as well as other exibilizing structural units to impart melt processability by conventional techniques, such as injection molding and extrusion. The commercially available PEI (trade name: Ultem) is the polymer synthesized by nucleophilic aromatic substitution between 1,3-bis(4-nitrophthalimido) benzene and the disodium salt of bisphenol A (Eq. 2-209) [Clagett, 1986]. This is the same reaction as that used to synthesize polyethersulfones and polyetherketones (Eq. 2-206) except that nitrite ion is displaced instead of halide. Polymerization is carried out at 80 130 C in a polar solvent (NMP, DMAC). It is also possible to synthesize the same polymer by using the diamine dianhydride reaction. Everything being equal (cost and availability of pure reactants), the nucleophilic substitution reaction is probably the preferred route due to the more moderate reaction conditions.

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The year 1925 was the turning point of the French market. The currency was stabilized, and a stronger government made at least temporary arrangements to settle pressing international problems. The price of rentes soared as France entered an easy-money period six years before England and America entered their easy-money periods. By 1930, 3% rentes were up to an average price of 871 4, to yield 3.44%, although newissue yields were higher. They had appreciated over 100% since 1925. The rentiers were winning back a little of their losses. The entire wartime decline in rentes had been made up. France briefly occupied the position of England in the late nineteenth century a citadel of hard money and low interest rates. In 1930 average yields were as follows:

You ll be introduced to the concept of chance electronics, the mechanics of clear illogic, and how you yourself can become a new species by actually melding your body with the electronics of the circuit You ll discover a new way to look at the lifespan not only of bent instrumemts but also all musical instruments Most important, the next chapter takes you inside circuit-bending s garden, an electronic zoological garden where you ll meet the creature instruments you re about to design..

C(CH3)2

2-209

This period of low French bond yields was brief. The financial crises of 1930 and 1931 were not French crises, but they brought French yields up. When after 1931 American and British yields plunged, the yields on 3% French rentes rose further and stabilized at around 4%, while new issues yielded above 5%. France had devalued her currency in 1925 1926 and was determined not to devalue again. Throughout the 1930 s, France struggled unsuccessfully to defend the franc in the face of worldwide depression and the looming prospect of war. By 1939 France was again a country of relatively high yields, as shown by the following table:

PEI is amorphous with a glass transition temperature of 215 C and continuous-use temperature of 170 180 C. The solvent and chemical resistance of PEI is comparable to that of polyimides as described above, except that it is soluble in partially halogenated organic solvents. Processability by conventional techniques coupled with a wide range of desirable properties has resulted in fast growth for this new polymer. PEI also has the advantage of not having any volatiles (water) produced during processing as occurs during the secondstage cyclization of poly(amic acids). Voids and strains can be generated as volatiles are lost during processing. PEI presently accounts for a major fraction of all polyimides. PEI resins are used in many industries: electrical electronic (circuit boards, radomes, hightemperature switches), transportation (fuel system components, transmission and jet engine components, lamp sockets), medical (surgical instrument handles, trays, and other items requiring sterilization by steam, ethylene oxide, chemical means, or g radiation), and consumer and business (microwave cookware, curling irons, food packaging, memory disks, fans for computer and other equipment). Polyamideimides (PAIs) (trade name: Torlon), containing both amide and imide functional groups in the polymer chain, are produced by the reaction of trimellitic anhydride (or a derivative) with various diamines (Eq. 2-210). PAI resins are amorphous polymers

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